Magnetism in coordination complexes

Three new metal-organic frameworks [MOF-525, Zr(6)O(4)(OH)(4)(TCPP-H(2))(3); MOF-535, Zr(6)O(4)(OH)(4)(XF)(3); MOF-545, Zr(6)O(8)(H(2)O)(8)(TCPP-H(2))(2), where porphyrin H(4)-TCPP-H(2) = (C(48)H(24)O(8)N(4)) and cruciform H(4)-XF = (C(42)O(8)H(22))] based on two new topologies, ftw and csq, have been synthesized and…

• SELÇUK DEMİR

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A series of structurally related pseudocubic metal cyanide clusters of Re(II) and 3d metal ions [{MX}4{Re(triphos)(CN)3}4] (M = Mn, Fe, Co, Ni, Zn; X = Cl, I, -OCH3) have been prepared, and their magnetic and electrochemical properties have been probed to evaluate the effect of changing the identity of the 3d metal io…

• FERDİ KARADAŞ

The structural, electronic, and magnetic properties of single layers of Iron Dichloride (FeCl2) were calculated using first principles calculations. We found that the 1T phase of the single layer FeCl2 is 0.17 eV/unit cell more favorable than its 1H phase. The structural stability is confirmed by phonon calculations.…

• HASAN ŞAHİN

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• HÜLYA KARA SUBAŞAT

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• AKIN AZİZOĞLU

Six coordination polymers of Zn(II) ions and three organic linkers namely, [Zn(μ 4 -tdc)(μ-bmeib) 0.5 ] n ( 1 ), [Zn(μ 4 -tdc)(μ-betib) 0.5 ] n ( 2 ), [Zn(μ 4 -tdc)(μ-bisopib) 0.5 ] n ( 3 ), [Zn(μ 4 -tdc)(μ-pbmeix) 0.5 ] n ( 4 ), [Zn(μ 4 -tdc)(μ-pbetix) 0.5 ] n ( 5 ), [Zn(μ 4 -tdc)(μ-pbisopix) 0.5 ] n ( 6 ), bisopib,…

• OKAN ZAFER YEŞİLEL

Six coordination polymers of Zn(II) ions and three organic linkers namely, [Zn(μ 4 -tdc)(μ-bmeib) 0.5 ] n ( 1 ), [Zn(μ 4 -tdc)(μ-betib) 0.5 ] n ( 2 ), [Zn(μ 4 -tdc)(μ-bisopib) 0.5 ] n ( 3 ), [Zn(μ 4 -tdc)(μ-pbmeix) 0.5 ] n ( 4 ), [Zn(μ 4 -tdc)(μ-pbetix) 0.5 ] n ( 5 ), [Zn(μ 4 -tdc)(μ-pbisopix) 0.5 ] n ( 6 ), bisopib,…

• MÜRSEL ARICI

Six coordination polymers of Zn(II) ions and three organic linkers namely, [Zn(μ 4 -tdc)(μ-bmeib) 0.5 ] n ( 1 ), [Zn(μ 4 -tdc)(μ-betib) 0.5 ] n ( 2 ), [Zn(μ 4 -tdc)(μ-bisopib) 0.5 ] n ( 3 ), [Zn(μ 4 -tdc)(μ-pbmeix) 0.5 ] n ( 4 ), [Zn(μ 4 -tdc)(μ-pbetix) 0.5 ] n ( 5 ), [Zn(μ 4 -tdc)(μ-pbisopix) 0.5 ] n ( 6 ), bisopib,…

• HAKAN ERER

Crystal structures are reported for the following complexes [Fe 3 O(OOCCMe 3 ) 6 (py) 3 ]ClO 4 ·0.5py, 1; [Mn 3 O(OOCCMe 3 ) 6 (py) 3 ]ClO 4 ·MeCN, 2; [Mn 3 O(OOCCMe 3 ) 6 (py) 3 ], 4; [Fe 3 O(OOCCMe 3 ) 6 (py) 3 ], 5. Crystal data are as follows: 1, system monoclinic, space group P 2 1 / n, a = 11.658(5) Å, b = 35.45…

Metal organic frameworks (MOFs) have received significant attention in recent years both from academia and industry since this new class of nanoporous materials has many potential advantages over traditional nanoporous materials in gas storage and separation applications. Hydrogen storage has been one of the most wide…

• SEDA KESKİN AVCI

Abstract A giant barocaloric effect (BCE) in a molecular material Fe3(bntrz)6(tcnset)6 (FBT) is reported, where bntrz = 4‐(benzyl)‐1,2,4‐triazole and tcnset = 1,1,3,3‐tetracyano‐2‐thioethylepropenide. The crystal structure of FBT contains a trinuclear transition metal complex that undergoes an abrupt spin‐state switch…

• ŞİNASİ BARIŞ EMRE