Treatment of agrochemical wastewater by subcritical water oxidation method: chemical composition and ion analysis of treated and untreated samples

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This work aimed at offering an effective and environmentally friendly approach to the real wastewater of an industrial agrochemicals production plant containing high amounts of many hazardous compounds that threaten human health. The removal of total organic carbon (TOC) (59.45%) and colour (97.92%) of the wastewater was achieved using subcritical water oxidation method. The fate of the detected compounds was followed by GC–MS analysis. Several pollutants such as phenol, fumaric acid, chlorpyrifos, penconazole, brassilexin, buprofezin, etoxazole, pyriproxyfen and 2-naphthalene-sulphonic acid which are bio-refractory and harmful to human health, were effectively degraded. Inorganic ions exist in the wastewater or formed through the process and their possible effects on the applied method were analysed. The central composite design was used to optimise the method and fully evaluate the single or combined effects of the method parameters on the removal rates. The precision of the applied design models was evaluated employing ANOVA, Regression coefficients and validation analysis. F and P and R2 values were obtained as 107.43, <0.0001, and 0.9898, respectively in the TOC removal model and 39.45, <0.0001, and 0.9726 in the colour removal model.