Advanced Polymer Synthesis and Characterization

click" transformation-based targeting strategies either through metabolic glycoengineering or stimuli-induced aggregation. This review focuses on the advances in the fabrication of ligand-based targeted micelles using the "click" reaction for ligand conjugation onto polymeric micelles and highlights recent application…

• AMITAV SANYAL

) groups, enabling further structural modification through click-chemistry pathways. Both modification routes resulted in partial conversion of the bromine functionalities. The incorporation of bromine functionalities and their subsequent chemical transformations provide a versatile platform for the preparation of fun…

In this study, biodegradable polyethylene glycol (PEG)-based block copolymer polyester was synthesized and evaluated by ring-opening polymerization (ROP). Poly(ethylene glycol-b-ɛ-caprolactone) [PEG-b-PCL] block copolymer was prepared by ring-opening polymerization of ɛ-caprolactone (ɛ-CL) in the presence of polyethyl…

ABSTRACT This study reports the synthesis of a macro‐RAFT agent based on poly(ɛ‐caprolactone) (PCL) via ring‐opening polymerization (ROP), which was subsequently used to prepare acrylate‐based block and block‐graft copolymers through RAFT polymerization. The macro‐RAFT agent enabled RAFT polymerization of glycidyl met…

In the plethora of different drug carrier materials, short chain-length block co-polymers exhibit advantages such as yielding reduced lower critical solution temperatures in aqueous solutions that makes micelle formation easier. Moreover, short chains that form smaller micelle dimensions allowing advantages in penetra…

Polymerizable surfactants have an important place in industrial applications and scientific research today. These substances offer effective solutions for providing protection against corrosion in various areas thanks to both their ability to reduce surface tension and their polymerization properties. Corrosion is a s…

Abstract Hierarchical materials in the natural world are often made through the self-assembly of amphiphilic molecules. Achieving similar structural complexity in synthetic materials requires understanding how various molecular parameters affect assembly behavior. In recent years, inverse surfactants─molecules with hy…

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Abstract Novel graft copolymers based on poly(vinylidene fluoride) (PVDF) bearing poly(2-alkyl-2-oxazoline) (POx) side chains, PVDF-g-POx, were synthesized via a two-step strategy. First, POx macromonomers end-functionalized with 2-(trifluoromethyl)acrylic acid (MAF-POx) were prepared through cationic ring-opening pol…

High Resolution Image Download MS PowerPoint Slide Microencapsulation enables the protection and controlled release of reactive liquids, however most characterization methods capture only endpoint properties. To address this gap, a real-time dual-probe approach using Focused Beam Reflectance Measurement (FBRM) and Par…

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Polietilen glikol (PEG) ve poli(L-laktik asit) (PLA) esaslı üçlü-blok kopolimerler, biyobozunur ve biyouyumlu özellikleri nedeniyle biyomedikal ve teknik tekstil uygulamalarında büyük ilgi görmektedir. Bu çalışmada, PLA-PEG-PLA üçlü-blok kopolimerleri mikrodalga destekli halka-açılma polimerizasyonu (mROP) yöntemi ile…