Article detail · 2003
Rotational isomerism in acetic acid: The first experimental observation of the high-energy conformer
- Year
- 2003
- Type
- article
Data source split
- YÖKSİS YÖKSİS article record
- YÖKSİS venue JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Catalog match (ISSN) Journal of the American Chemical Society
- OpenAlex OpenAlex enrichment (abstract, citations, topics)
Abstract
OpenAlex · English
The high-energy conformer of acetic acid (cis-AA) is produced in an Ar matrix by vibrational excitation of the OH stretching overtone of the ground conformational state (trans-AA). IR-absorption spectroscopy provides a clear identification of the reaction product. cis-AA converts back to trans-AA in a time scale of minutes at 8 K by tunneling.
Topics
Citations
OpenAlex cited_by_count. Not a WoS or Scopus citation count; those sources have no separate column here.
124 citations
OpenAlex cited_by_count (cache / database)
56 publications in the local catalog that cite this work (OpenAlex reference match; not the full global list).
- Formic and acetic acids in a nitrogen matrix: Enhanced stability of the higher-energy conformer 2010
- Rotational isomerism of acetic acid isolated in rare-gas matrices:: Effect of medium and isotopic substitution on IR-induced isomerization quantum yield and cis→trans tunneling rate 2004
- Photochemistry and Vibrational Spectroscopy of the Trans and Cis Conformers of Acetic Acid in Solid Ar 2004
- Internal rotation in propionic acid: Near-infrared-induced isomerization in solid argon 2005
- Conformational Switching in Pyruvic Acid Isolated in Ar and N2 Matrixes: Spectroscopic Analysis, Anharmonic Simulation, and Tunneling 2015
- Rotational isomerization of small carboxylic acids isolated in argon matrices: Tunnelling and quantum yields for the photoinduced processes 2005
- Spontaneous tunneling and near-infrared-induced interconversion between the amino-hydroxy conformers of cytosine 2012
- NIR-laser-induced selective rotamerization of hydroxy conformers of cytosine 2010
- Near-IR laser generation of a high-energy conformer of L-alanine and the mechanism of its decay in a low-temperature nitrogen matrix 2013
- Conformational Switching Induced by Near-Infrared Laser Irradiation 2009