Article detail · 2018
Conformational control over an aldehyde fragment by selective vibrational excitation of interchangeable remote antennas
- Year
- 2018
- Type
- article
Data source split
- YÖKSİS YÖKSİS article record
- YÖKSİS venue CHEMICAL COMMUNICATIONS
- Catalog match (ISSN) Chemical Communications
- OpenAlex OpenAlex enrichment (abstract, citations, topics)
Abstract
OpenAlex · English
We apply interchangeable vibrational antennas (OH or NH2 group) to achieve unprecedented conformational control over the heavy aldehyde fragment in 2-formyl-2H-azirine. The two aldehyde conformers were manipulated bi-directionally, using selective vibrational excitation with narrowband near-infrared (NIR) light tuned at the wavenumbers corresponding to OH and NH2 stretching overtones and combination modes.
Topics
Citations
OpenAlex cited_by_count. Not a WoS or Scopus citation count; those sources have no separate column here.
16 citations
OpenAlex cited_by_count (cache / database)
15 publications in the local catalog that cite this work (OpenAlex reference match; not the full global list).
- Effects of Entangled IR Radiation and Tunneling on the Conformational Interconversion of 2-Cyanophenol 2019
- IR-induced and tunneling reactions in cryogenic matrices: the (incomplete) story of a successful endeavor 2022
- Switching on H-Tunneling through Conformational Control 2021
- Bond-Breaking/Bond-Forming Reactions by Vibrational Excitation: Infrared-Induced Bidirectional Tautomerization of Matrix-Isolated Thiotropolone 2020
- Kinetically unstable 2-isocyanophenol isolated in cryogenic matrices: Vibrational excitation, conformational changes and spontaneous tunneling 2020
- Inducing molecular reactions by selective vibrational excitation of a remote antenna with near-infrared light 2021
- Selective conformational control by excitation of NH imino vibrational antennas 2019
- Conformational isomerizations triggered by vibrational excitation of second stretching overtones 2019
- Differential Tunneling-Driven and Vibrationally-Induced Reactivity in Isomeric Benzazirines 2022
- Photochemical Generation and Characterization of C-Aminophenyl-Nitrilimines: Insights on Their Bond-Shift Isomers by Matrix-Isolation IR Spectroscopy and Density Functional Theory Calculations 2024