Article detail · 2006
Synthesis crystal structure and magnetic behaviour of a mononuclear Fe III Schiff base metal complex
ZEITSCHRIFT FUR KRISTALLOGGRAPHIE
- Year
- 2006
- ISSN
2194-4946- Type
- article
Data source split
- YÖKSİS YÖKSİS article record
- OpenAlex OpenAlex enrichment (abstract, citations, topics)
Abstract
English (OpenAlex)
Abstract A complex from Fe(II) and a hexa-dentate linear ligand containing O2N4 donor atoms were prepared and the structure enlightened with X-ray diffraction. The Fe(II) ion in the complex was seen to be oxidized to form a Fe(III) complex, [C20H24Cl3N4O2]Fe and the three chloride ions were situated at a distance of Fe…Cl(1) 3.976(5), Fe…Cl(2) 4.479(3) and Fe…Cl(3) 7.509(4) Å outside the coordination sphere. The Fe(III) ion has an octahedral coordination sphere and as expected the two oxygen donor atoms are coordinated in a -cis position. The Fe—O, Fe—Nimin and Fe—Namine distances are 1.880(3) Å, 1.931(4) Å and 2.004(4) Å, respectively.
Topics
- Metal complexes synthesis and properties
- Magnetism in coordination complexes
- Lanthanide and Transition Metal Complexes
Primary topic Metal complexes synthesis and properties