Article detail · 2016
Synthesis and Crystal Structure of a New Phthalonitrile and Its Phthalocyanines Bearing Diamagnetic Metals
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Year
- 2016
- ISSN
1553-3174- Type
- article
Data source split
- YÖKSİS YÖKSİS article record
- OpenAlex OpenAlex enrichment (abstract, citations, topics)
Abstract
English (OpenAlex)
A new phthalonitrile (1) was synthesized and characterized using different spectroscopic techniques, elemental analyses, and single-crystal X-ray diffractometry. The crystal structure is stabilized by p-p stacking interactions between the benzene rings with two methyl groups. Metal free (2), Mg (3), Zn (4), and Pd (5) phthalocyanine complexes of the phthalonitrile were synthesized with metal salts, and the complexes showed good solubility in a wide range of organic solvents with no aggregation observed within a wide concentration range. The complexes were characterized by elemental analyses, UV-Vis, FT-IR, NMR, and mass spectrometry, and show good prospect for application in photodynamic therapy of cancer.
Topics
- Porphyrin and Phthalocyanine Chemistry
- Photochromic and Fluorescence Chemistry
- Photochemistry and Electron Transfer Studies
Primary topic Porphyrin and Phthalocyanine Chemistry