Organic and Molecular Conductors Research

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A series of structurally related pseudocubic metal cyanide clusters of Re(II) and 3d metal ions [{MX}4{Re(triphos)(CN)3}4] (M = Mn, Fe, Co, Ni, Zn; X = Cl, I, -OCH3) have been prepared, and their magnetic and electrochemical properties have been probed to evaluate the effect of changing the identity of the 3d metal io…

• FERDİ KARADAŞ

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Abstract Despite rapid improvements in efficiency, long‐term stability remains a challenge limiting the future up‐scaling of perovskite solar cells (PSCs). Although several approaches have been developed to improve the stability of PSCs, applying ammonium passivation materials in bilayer configuration PSCs has drawn i…

• SEÇKİN AKIN

Abstract A giant barocaloric effect (BCE) in a molecular material Fe3(bntrz)6(tcnset)6 (FBT) is reported, where bntrz = 4‐(benzyl)‐1,2,4‐triazole and tcnset = 1,1,3,3‐tetracyano‐2‐thioethylepropenide. The crystal structure of FBT contains a trinuclear transition metal complex that undergoes an abrupt spin‐state switch…

• ŞİNASİ BARIŞ EMRE

Novel fused donor-acceptor dyad (TTF-Q or D-A) and acceptor-donor-acceptor triad (Q-TTF-Q or A-D-A) incorporating the donor tetrathiafulvalene (TTF) and the acceptor p-benzoquinone (Q) have been synthesized. The solution UV-vis spectra of these molecules display a low-energy absorption band that is attributed to an in…

• YÜCEL ŞAHİN

The reactivity of the redox-active tetracarboxylic acid derived from the tetrathiafulvalene (TTF-TC)H(4) with alkaline cations (K, Rb, Cs) is reported. The exploration of various experimental parameters (temperature, pH) led to the formation of four crystalline three-dimensional coordination polymers formulated M(2)(T…

• REZAN DEMİR ÇAKAN

New electron-deficient and soluble indenofluorene-based and bisindenofluorene-based ladder-type building blocks embedding carbonyl and dicyanovinylene functionalities were synthesized, and their optical and electrochemical properties were characterized. These derivatives exhibit optical band gaps of 1.83 to 2.44 eV an…

• HAKAN USTA

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• AHMET ATAÇ

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• BEKİR SALİH

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• AHMET ALTINDAL