Makale detayı · 2025
Multicomponent synthesis of stereogenic-at-boron fluorophores (BOSPYR) from boronic acids, salicylaldehydes, and 2-formylpyrrole hydrazones
YÖKSİS
OpenAlex
Açık erişim · hybrid
SJR Q1
JCR Q2
Atıf 2
Yüzdelik 43.2%
FWCI 0.18
- Yıl
- 2025
- ISSN
1359-7345- Tür
- article
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Özet
İngilizce (OpenAlex)
in the visible region, indicating efficient asymmetry induction to the chromophore. The X-ray molecular structure of 1a shows that the chromophore deviates from planarity by 17.2°, which may contribute significantly to the inherent chirality of the fluorophore. A computational examination of excited states by time-dependent density functional theory (TD-DFT) identifies the emission mechanism as arising from a locally-excited (LE) state.
Konular
- Luminescence and Fluorescent Materials
- Molecular Sensors and Ion Detection
- Organoboron and organosilicon chemistry
Birincil konu Luminescence and Fluorescent Materials