Organoboron and organosilicon chemistry

Vanillin/cyclodextrin inclusion complex nanofibers (vanillin/CD-IC NFs) were successfully obtained from three modified CD types (HPβCD, HPγCD and MβCD) in three different solvent systems (water, DMF and DMAc) via an electrospinning technique without using a carrier polymeric matrix. Vanillin/CD-IC NFs with uniform and…

• SEMRAN İPEK

Vanillin/cyclodextrin inclusion complex nanofibers (vanillin/CD-IC NFs) were successfully obtained from three modified CD types (HPβCD, HPγCD and MβCD) in three different solvent systems (water, DMF and DMAc) via an electrospinning technique without using a carrier polymeric matrix. Vanillin/CD-IC NFs with uniform and…

• ENGİN DURGUN
• SEMRAN İPEK

The complete reductive cleavage of the triple bond in carbon monoxide was achieved using a lithium disilenide at room temperature. The C-C-coupled product can be regarded as a silanone dimer with pending alkyne and silirene moieties and incorporates two equivalents of CO per disilenide unit. A formation mechanism via…

• AKIN AZİZOĞLU

The complete reductive cleavage of the triple bond in carbon monoxide was achieved using a lithium disilenide at room temperature. The C-C-coupled product can be regarded as a silanone dimer with pending alkyne and silirene moieties and incorporates two equivalents of CO per disilenide unit. A formation mechanism via…

• CEM BURAK YILDIZ

Two novel D–A (donor–acceptor) and one D–A–D small molecules containing mesitylborane as an acceptor and triphenylamine as a donor, linked through a thieno[3,2- b ]thiophene π-conjugated spacer, are synthesized and characterized.

• EMİNE TEKİN

One extremely short and two relatively long BB bonds are found for the B3 ring of compounds 1 and 2. This characteristic of three-membered, two-electron double aromatic compounds was predicted as early as 1994 and has now been experimentally realized for the first time. A=SiMe3.

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• ŞÜKRÜ BEYDEMİR

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• MESUT IŞIK

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• CÜNEYT TÜRKEŞ
• KASIM TAKIM

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• ADEM NECİP
• AHMET KILIÇ

Ring-opening metathesis polymerization (ROMP) was used to synthesize novel norbornene based polycarboxy- ( d-Poly 3a and d-Poly 3b ) and polysulfobetaines ( Poly 3c ) using the third generation Grubbs’ catalyst (G3) as the initiator. Hydrophobicity of the polycarboxybetaines was varied by changing the bridging group o…

Abstract Herein we report a new method for the synthesis and characterization of PVP‐stabilized palladium(0) nanoclusters and their enhanced catalytic activity in Suzuki coupling and Heck reactions of aryl bromides with phenylboronic acid and styrene, respectively, under mild conditions. The PVP‐stabilized palladium(0…

• ÖNDER METİN