Makale detayı · 1994 · article
Octakis alkylthio substituted phthalocyanines and their interactions with silver I and palladium II ions
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- YÖKSİSYÖKSİS makale kaydı
- YÖKSİS dergi adıJournal of the Chemical Society, Dalton Transactions
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Özet
Metal-free phthalocyanines and metal phthalocyaninates (M = Ni, Cu, Co or Zn) carrying eight alkylthio-groups on peripheral positions have been synthesised from 4,5-bis(alkylthio)phthalonitrile and 1,8-diazabicyclo[5.4.0]undec-7-ene (dbu) or the corresponding anhydrous metal salt [NiCl2, CuCl, CoCl2 or Zn(O2CMe)2]. The resulting compounds reacted with silver(I) or palladium(II) salts to form complexes with a phthalocyanine:metal ratio of 1 : 4. Spectrophotochemical investigation of these reactions revealed that complexation with AgI results in aggregation, while the addition of PdII destroys the aggregation and yields a new Q band at 720 nm.
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Yerel katalogda bu makaleye atıf yapan 252 yayın (OpenAlex referans eşleşmesi; tam dünya listesi değildir).
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