Highly Efficient Deep-Blue Electroluminescence Based on a Solution-Processable A−π–D−π–A Oligo(p-phenyleneethynylene) Small Molecule

İngilizce (OpenAlex)

The development of solution-processable fluorescent small molecules with highly efficient deep-blue electroluminescence is of growing interest for organic light-emitting diode (OLED) applications. However, high-performance deep-blue fluorescent emitters with external quantum efficiencies (EQEs) over 5% are still scarce in OLEDs. Herein, a novel highly soluble oligo( p -phenyleneethynylene)-based small molecule, 1,4-bis((2-cyanophenyl)ethynyl)-2,5-bis(2-ethylhexyloxy)benzene (2EHO–CNPE), is designed, synthesized, and fully characterized as a wide band gap (2.98 eV) and highly fluorescent (Φ PL = 0.90 ( solution ) and 0.51 ( solid-state )) deep-blue emitter. The new molecule is functionalized with cyano (-CN)/2-ethylhexyloxy (-OCH 2 CH(C 2 H 5 )C 4 H 9 ) electron-withdrawing/-donating substituents, and ethynylene is used as a π-spacer to form an acceptor (A)−π–donor (D)−π–acceptor (A) molecular architecture with hybridized local and charge transfer (HLCT) excited states. Physicochemical and optoelectronic characterizations of the new emitter were performed in detail, and the single-crystal structure was determined. The new molecule adopts a nearly coplanar π-conjugated framework packed via intermolecular “C–H···π” and “C–H···N” hydrogen bonding interactions without any π–π stacking. The OLED device based on 2EHO–CNPE shows an EQE max of 7.06% (EQE = 6.30% at 200 cd/m 2 ) and a maximum current efficiency (CE max ) of 5.91 cd/A (CE = 5.34 cd/A at 200 cd/m 2 ) with a deep-blue emission at CIE of (0.15, 0.09). The electroluminescence performances achieved here are among the highest reported to date for a solution-processed deep-blue fluorescent small molecule, and, to the best of our knowledge, it is the first time that a deep-blue OLED is reported based on the oligo( p -phenyleneethynylene) π-framework. TDDFT calculations point to facile reverse intersystem crossing (RISC) processes in 2EHO–CNPE from high-lying triplet states to the first singlet excited state (T 2 /T 3 → S 1 ) ( hot-exciton channels ) that enable a high radiative exciton yield (η r ∼ 69%) breaking the theoretical limit of 25% in conventional fluorescent OLEDs. These results demonstrate that properly designed fluorescent oligo( p -phenyleneethynylenes) can be a key player in high-performance deep-blue OLEDs.