Makale detayı · 2007
New Copper II and Nickel II Complexes of 4 Morpholinoacetophenone Thiosemicarbazone Structural Electrochemical and Antimicrobial Studies
- Yıl
- 2007
- ISSN
1001-604X- Tür
- article
Veri kaynağı ayrımı
- YÖKSİS YÖKSİS makale kaydı
- OpenAlex OpenAlex zenginleştirmesi (özet, atıf, konular)
Özet
İngilizce (OpenAlex)
Abstract 4‐Morpholinoacetophenone thiosemicarbazone, MAPT, and its nickel(II) and copper(II) complexes have been prepared and characterized by elemental analysis, magnetic susceptibility, spectral methods (FT‐IR, 1H NMR) and cyclic voltammetry. Electrochemical behaviors of the complexes have been studied by cyclic voltammetry in DMF media showing metal centered reduction processes for both of them. The redox properties, nature of the electrode processes and the stability of the complexes were discussed. [Cu(MAPT)2]Cl2 complex shows Cu(II)/Cu(I) couple and quasi‐reversible wave associated with the Cu(III)/Cu(II) process. The reduction/oxidation potential values depend on the structures of complexes. Also, the antimicrobial activities of these complexes were determined against S. aureus, E. coli and B. subtilis.
Konular
- Metal complexes synthesis and properties
- Electrochemical Analysis and Applications
- Inorganic and Organometallic Chemistry
Birincil konu Metal complexes synthesis and properties