Palladium recovery from spent Pd plating solutions using Lewatit TP 214 resin

İngilizce (OpenAlex)

ABSTRACT This study aims to explore the recovery of palladium (Pd(II)) ions using Lewatit TP 214 resins. Waste Pd(II) ions with ammonia complex procured from a precious metal plating were selected as the source solution. In the experimental studies, two stock solutions of 60 ppm Pd(II) with a pH value of 4.0 and 7.5 were prepared as initial solutions. The experiments were performed by altering four parameters: solution pH, time 15–180 min, temperature 25°C–60°C, and amount of resin 100–400 mg. It was proved that the recovery percentage increased with higher temperature and resin at lower pH values. The Pd(II) recovery percentage increased with a temperature rise, reaching 100% after 40 min at pH 4.0 and 60°C. On the other hand, a bit lower efficiency (95%) was attained after 180 min at pH 7.5 and 60°C. Using Lewatit TP 214, the computed activation energies for Pd(II) recovery are 17.73 and 15.62 kJ/mol at pH 4.0 and 7.5, respectively. Considering these activation energy values, a mixed mechanism dominated the recovery of Pd(II).