Makale detayı · 2017 · article
Innovative Carbon Dioxide-Capturing Organic Solvent: Reaction Mechanism and Kinetics
Veri kaynağı ayrımı
- YÖKSİSYÖKSİS makale kaydı
- YÖKSİS dergi adıChemical Engineering Technology
- Katalog eşleşmesi (ISSN)Chemical Engineering and Technology
- OpenAlexOpenAlex zenginleştirmesi (özet, atıf, konular)
- Semantic Scholaratıf sayısı (OpenAlex ile birleştirilmez)
Özet
Abstract The reaction rates of CO2 with an innovative CO2‐capturing organic solvent (CO2COS), consisting of blends of 2‐tert‐butyl‐1,1,3,3‐tetramethylguanidine (BTMG) and 1‐propanol, were obtained as function of BTMG concentration and temperature. A stopped‐flow apparatus with conductivity detection was used. The reaction was modeled by means of a modified termolecular reaction mechanism which resulted in a second‐order rate constant, and activation energies were calculated for a defined temperature range. Quantum chemical calculations at the B3LYP/6‐31G(d) level also produced the activation energy of this reaction system which strongly supports the experimental findings.
Konular
Atıflar
OpenAlex cited_by_count. WoS veya Scopus atıf sayısı değildir; o kaynaklar için ayrı kolon yoktur.
9atıfOpenAlex · cited_by_count (önbellek / veritabanı)
Yerel katalogda bu makaleye atıf yapan 8 yayın (OpenAlex referans eşleşmesi; tam dünya listesi değildir).
- 2017 Kinetics of reaction between CO2 and ionic liquid-carbon dioxide binding organic liquid hybrid systems: Analysis of gas-liquid absorption and stopped flow experimentsAtıf 37 · OpenAlex
- 2021 Capture of Carbonyl Sulfide by Organic Liquid Mixtures: A Systematic DFT InvestigationAtıf 12 · OpenAlex
- 2020 The development of reaction kinetics for CO2 absorption into novel solvent systems: Frustrated Lewis pairs (FLPs)Atıf 4 · OpenAlex
- 2020 The development of reaction kinetics for CO2 absorption into novel solvent Frustrated Lewis (FLPs)Atıf 4 · OpenAlex
- 2020 The development of reaction kinetics for CO2 absorption into novel solvent systems: Frustrated Lewis pairs (FLPs)Atıf 4 · OpenAlex
- 2021 Effect of non-aqueous solvents on kinetics of carbon dioxide absorption by (Bu3P)-Bu-t/B(C6F5)(3) frustrated Lewis pairsAtıf 2 · OpenAlex
- 2021 Effect of non-aqueous solvents on kinetics of carbon dioxide absorption by Bu3P/B(C6F5)3 frustrated Lewis pairsAtıf 2 · OpenAlex
- 2018 Theoretical investigation of carbon dioxide capture by aqueous boric acid solution: A termolecular reaction mechanismAtıf 1 · OpenAlex