Makale detayı · 2019
An anomalous addition of chlorosulfonyl isocyanate to a carbonyl group: the synthesis of ((3aS,7aR,E)-2-ethyl-3-oxo-2,3,3a,4,7,7a-hexahydro-1H-isoindol-1-ylidene)sulfamoyl chloride
Beilstein Journal of Organic Chemistry
YÖKSİS
OpenAlex
Açık erişim · diamond
SJR Q2
JCR Q2
Atıf 3
Yüzdelik 38.9%
FWCI 0.17
- Yıl
- 2019
- ISSN
1860-5397- Tür
- article
Veri kaynağı ayrımı
- YÖKSİS YÖKSİS makale kaydı
- OpenAlex OpenAlex zenginleştirmesi (özet, atıf, konular)
Özet
İngilizce (OpenAlex)
In this study, we developed a new addition reaction of chlorosulfonyl isocyanate (CSI), starting from 2-ethyl-3a,4,7,7a-tetrahydro-1H-isoindole-1,3(2H)-dione. The addition reaction of CSI with 2-ethyl-3a,4,7,7a-tetrahydro-1H-isoindole-1,3(2H)-dione resulted in the formation of ylidenesulfamoyl chloride, whose exact configuration was determined by X-ray crystal analysis. We explain the mechanism of product formation supported by theoretical calculations.
Konular
- Fluorine in Organic Chemistry
- Synthesis and Catalytic Reactions
- Synthesis and Reactions of Organic Compounds
Birincil konu Fluorine in Organic Chemistry