Makale detayı · 2014
Total Syntheses of Multicaulins via Oxidative Photocyclization of Stilbenes
YÖKSİS
OpenAlex
SJR Q1
JCR Q1
Atıf 7
Yüzdelik 62.1%
FWCI 0.39
- Yıl
- 2014
- ISSN
0163-3864- Tür
- article
Veri kaynağı ayrımı
- YÖKSİS YÖKSİS makale kaydı
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Özet
İngilizce (OpenAlex)
The Wittig reaction of 3-isopropyl-4-methoxybenzaldehyde and 2,3-dimethylbenzylphosphonium bromide afforded the corresponding stilbene mixture 16. Oxidative photocyclization of stilbene 16 with iodine facilitated the first total synthesis of 7-isopropyl-6-methoxy-1,2-dimethylphenanthrene, multicaulin (1). The O-demethylation of 1 with BBr3 afforded the 7-isopropyl-1,2-dimethylphenanthren-6-ol, O-demethylmulticaulin (2).
Konular
- Bioactive natural compounds
- Phytochemistry and Biological Activities
- Alkaloids: synthesis and pharmacology
Birincil konu Bioactive natural compounds