Makale detayı · 2002 · article
Growth kinetics of CdSe nanoparticles in glass
Veri kaynağı ayrımı
- YÖKSİSYÖKSİS makale kaydı
- YÖKSİS dergi adıJournal of Physics: Condensed Matter
- Katalog eşleşmesi (ISSN)Journal of Physics Condensed Matter
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Özet
The growth of CdS 0.08 Se 0.92 nanoparticles in glass is studied through the analysis of optical absorption spectra with the help of a quantized-state effective-mass model in which the conduction band effective mass is particle size dependent. The glass includes nanoparticles with an initial average size of ~1.4 nm on cooling down to room temperature from the melt at ~1000 °C. Particles grow by diffusion of the reactants onto the surface of initially formed nuclei upon heat treatment between 575 and 675 °C. Combined use of Arrhenius plots and the model yields an activation energy of ~500 kJ mol -1 .
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