Makale detayı · 2022 · article
Synthesis of Novel Artemisinin Derivatives and Their Electrochemical Properties
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Özet
Abstract In present, new artemisinin‐based organic compounds ( 1 – 6 ) are designed and synthesized in excellent yields (up to 97 %) via Steglich Esterification reactions. All new artemisinin derivatives are tested as anode catalysts for hydrazine electrooxidation reactions with electrochemical methods in 1 M KOH/0.5 M N 2 H 4 solution. Hybrid molecule 1 exhibits the best catalytic activity in hydrazine electrooxidation reaction with 2.28 mA cm −2 value. Moreover, response surface methodology (RSM) is applied to investigate of optimum electrode conditions. By using optimum conditions, hydrazine electrooxidation is obtained as 3.55324 mA cm −2 . As a result, artemisinin‐based hybrid compounds may be alternative, and next‐generation anode catalyst for direct hydrazine fuel cells.
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