Homogeneous catalytic hydroformylation of 1 octene in supercritical carbon dioxide using a novel rhodium catalyst with fluorinated arylphosphine ligands

OpenAlex İngilizce

A novel rhodium-based catalyst was developed for homogeneous hydroformylation in supercritical carbon dioxide. The catalyst, trans -RhCl(CO)(P( p -CF 3 C 6 H 4 ) 3 ) 2, has in the supercritical fluid reaction mixture moderate solubility (>5.5 mM), 2 orders of magnitude greater than most conventional metal−triphenylphosphine catalysts. Homogeneous catalytic hydroformylation of 1-octene using the novel catalyst was carried out at 343 K and 272 atm. Conversion of 1-octene was complete, with a normal/branched aldehyde ratio of ca. 2.4 and negligible hydrogenation or isomerization products. The catalyst was also recoverable in its original form, as confirmed by 31 P NMR and FTIR spectroscopy.