Makale detayı · 2006
Synthesis and characterization of new copperphthalocyanine carrying mixed donor macrocyclic moieties
Journal of Coordination Chemistry
- Yıl
- 2006
- ISSN
0095-8972- Tür
- article
Veri kaynağı ayrımı
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Özet
İngilizce (OpenAlex)
The new phthalocyanine peripherally substituted with a twelve-membered dioxadiaza macrocycle was synthesized by cyclotetramerization of 1,2-bis(2-{4′-[(4′-methylphenyl)-sulphonyl]-1′,7′-dioxa-4′,10′-diazacyclododecane})-4,5-dicyanobenzene (4) which was obtained from 1,2-bis(2-{4′-[(4′-methylphenyl)sulphonyl]-1′,7′-dioxa-4′,10′-diazacyclododecane})-4,5-dibromobenzene (3). Metallophthalocyanine was also prepared by the reaction of the dicyano-substituted macrocycle in the presence of anhydrous CuCN. The new compounds were characterized by a combination of elemental analysis, 1H and 13C NMR, IR, electronic and mass spectroscopies.
Konular
- Porphyrin and Phthalocyanine Chemistry
- Metal-Catalyzed Oxygenation Mechanisms
- Magnetism in coordination complexes
Birincil konu Porphyrin and Phthalocyanine Chemistry