Makale detayı · 2014
Sunlight induced atom transfer radical polymerization by using dimanganese decacarbonyl
Dergi
Polym. Chem.ISSN 1759-9954
ISSN kaydı başka bir dergiye işaret ediyor; ad YÖKSİS kaydından.
- Yıl
- 2014
- Tür
- article
Veri kaynağı ayrımı
- YÖKSİS YÖKSİS makale kaydı
- YÖKSİS dergi adı Polym. Chem.
- Katalog eşleşmesi (ISSN) Polymer Chemistry
- OpenAlex OpenAlex zenginleştirmesi (özet, atıf, konular)
Özet
OpenAlex · İngilizce
A new photoredox catalyst system for atom transfer radical polymerization is developed on the basis of visible light photocatalysis using dimanganese decacarbonyl (Mn2(CO)10) that initiates and controls the polymerization at ambient temperature. The polymerization was performed by a Mn2(CO)10–alkyl halide system with visible- or sunlight in the presence of parts per million (ppm) copper catalysts. The photogenerated ˙Mn(CO)5 radicals are not only able to abstract halogen atoms from alkyl halides to generate carbon centered radicals but also reduce the CuIIBr2 to CuIBr directly, which was used as an activator in the Atom Transfer Radical Polymerization (ATRP) of vinyl monomers such as methyl methacrylate, methyl acrylate and styrene. The method was also used to synthesize graft copolymers from commercially available poly(vinyl chloride) without additional modification.
Konular
Atıflar
OpenAlex cited_by_count. WoS veya Scopus atıf sayısı değildir; o kaynaklar için ayrı kolon yoktur.
166 atıf
OpenAlex cited_by_count (önbellek / veritabanı)
Yerel katalogda bu makaleye atıf yapan 43 yayın (OpenAlex referans eşleşmesi; tam dünya listesi değildir).
- Photomediated controlled radical polymerization 2016
- Photoinitiated atom transfer radical polymerization Current status and future perspectives 2014
- Photoinduced Atom Transfer Radical Polymerization Using Semiconductor Nanoparticles 2014
- Photochemically Mediated Atom Transfer Radical Polymerization Using Polymeric Semiconductor Mesoporous Graphitic Carbon Nitride 2014
- Photochemically Mediated Atom Transfer Radical Polymerization Using Polymeric Semiconductor Mesoporous Graphitic Carbon Nitride 2014
- Photoinitiated ATRP in Inverse Microemulsion 2013
- Photoinitiated ATRP in Inverse Microemulsion 2013
- Externally stimulated click reactions for macromolecular syntheses 2016
- Externally stimulated click reactions for macromolecular syntheses 2016
- Living Cationic Polymerization of Vinyl Ethers through a Photoinduced Radical Oxidation/Addition/Deactivation Sequence 2017