Makale detayı · 2013
Nucleophilic Reactivity of Ethers Against Terminal Epoxides in the Presence of BF3: A Mechanistic Study
YÖKSİS
OpenAlex
SJR Q2
JCR Q3
Atıf 6
Yüzdelik 61.8%
FWCI 0.45
- Yıl
- 2013
- ISSN
0018-019X- Tür
- article
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Özet
İngilizce (OpenAlex)
Abstract In the presence of BF3, a series of symmetrical and unsymmetrical ethers reacted with epichlorohydrin and 2‐[(benzyloxy)methyl]oxirane, two terminal epoxides, to afford 1‐alkoxy‐3‐chloropropan‐2‐ol and 1‐alkoxy‐3‐(benzyloxy)propan‐2‐ol. The cleavage of unsymmetrical ethers occurred via an SN2 or SN1 mechanism. Secondary epoxides did not give similar ring‐opening products.
Konular
- Fluorine in Organic Chemistry
- Oxidative Organic Chemistry Reactions
- Organic and Inorganic Chemical Reactions
Birincil konu Fluorine in Organic Chemistry