Insights into nonlinear adsorption kinetics and isotherms of vanadium using magnetised coal-polyaniline

OpenAlex İngilizce

ABSTRACT Remediation of the polluted environment has become a major concern in the 21st century. Because of its cost-benefit, ease of application, and efficacy towards the removal of pollutants, the adsorption technique has gained acceptance. In this study, adsorption kinetics of vanadium onto magnetized coal-polyaniline (MC-PANI) are investigated under batch experiments. Isotherms and kinetics are assessed using average relative error deviation, Marquardt’s percent standard error deviation, the hybrid fractional error function, chi-square (χ 2 ), Spearman, and the sum of the squares of the errors (SSE). Comparing all of the error functions, nonlinear models explain the adsorption of vanadium better than linear models. According to the Boyd model, the adsorption of vanadium occurs in two stages. The maximum adsorption capacity of MC-PANI is 66.20 mg V/g (C 0 = 50 mg/L, pH = 5, dose = 1.5 g/L, T = 25°C). Based on Freundlich’s dimensionless constant, which determines the driving force of adsorption, adsorption was less favored during the adsorption of vanadium; both amine and Fe 3 O 4 participated in the removal of vanadium through ligand or ion exchange.