Hydrogen Evolution Reaction Performance of Ni-Co-Coated Graphene-Based 3D Printed Electrodes

OpenAlex İngilizce

High Resolution Image Download MS PowerPoint Slide Additive manufacturing has been a very promising topic in recent years for research and development studies and industrial applications. Its electrochemical applications are very popular due to the cost-effective rapid production from the environmentally friendly method. In this study, three-dimensional (3D) printed electrodes are prepared by Ni and Co coatings in different molar ratios. Different Ni/Co molar ratios ( x: y ) of the Ni/Co/ x: y alloys are prepared as 1:1, 1:4, and 4:1 and they are named Ni/Co/1:1, Ni/Co/4:1, and Ni/Co/1:4, respectively. According to the results, when the 3D electrode samples are coated with Ni and Co at different molar ratios, the kinetic performance of the NiCo-coated 3D electrode samples for hydrogen evolution reaction is enhanced compared to that of the uncoated 3D electrode sample. The results indicate that the Ni/Co/1:4-coated 3D electrode has the highest kinetic activity for hydrogen evolution reactions (HERs). The calculated Tafel′s slope and overpotential value (η 10 ) for HER are determined as 164.65 mV/dec and 101.92 mV, respectively. Moreover, the Ni/Co/1:4-coated 3D electrode has an 81.2% higher current density than the other electrode. It is observed that the 3D printing of the electrochemical electrodes is very promising when they are coated with Ni–Co metals in different ratios. This study provides a new perspective on the use of 3D printed electrodes for high-performance water electrolysis.