Makale detayı · 2016
Microwave assisted synthesis of novel amide based chiral tripodal receptors for recognition of cation and anion sensors
- Yıl
- 2016
- ISSN
1551-7012- Tür
- article
Veri kaynağı ayrımı
- YÖKSİS YÖKSİS makale kaydı
- OpenAlex OpenAlex zenginleştirmesi (özet, atıf, konular)
Özet
İngilizce (OpenAlex)
Five novel amide based chiral tripodal receptors were synthesized under microwave irradiation by reacting nitrilotriacetic acid with chiral amino alcohols in a solvent-free medium with high yields (≥ 90%).The recognition affinities of these tripodal receptors were investigated towards anions and chiral organic ammonium cations using 1 H NMR titration method.The results show that receptor 1 displays more affinity against anions compared with other receptors and the tripodal receptor 4 demonstrated a significant enantiomeric selectivity towards the (R)naphthylethylammonium perchlorate (ERF 54%).
Konular
- Molecular Sensors and Ion Detection
- Analytical Chemistry and Chromatography
Birincil konu Molecular Sensors and Ion Detection